A facile method for the synthesis of a sintering dense nano-grained Na3Zr2Si2PO12 Na+-ion solid-state electrolyte

Guanming Yang; Yanfang Zhai; Jianyao Yao; Shufeng Song; Weiping Tang; Zhaoyin Wen; Li Lu; Ning Hu

doi:10.1039/D0CC07261C

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A facile method for the synthesis of a sintering dense nano-grained Na₃Zr₂Si₂PO₁₂ Na⁺-ion solid-state electrolyte†

Guanming Yang,^a Yanfang Zhai,^a Jianyao Yao,^a Shufeng Song,

*^a Weiping Tang,^b Zhaoyin Wen,

^c Li Lu^d and Ning Hu

Author affiliations

* Corresponding authors

^a College of Aerospace Engineering, Chongqing University, Chongqing 400044, China
E-mail: sfsong@cqu.edu.cn

^b State Key Laboratory of Space Power-Sources Technology, Shanghai Institute of Space Power-Sources, Shanghai 200245, China

^c CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

^d Department of Mechanical Engineering, National University of Singapore, Singapore

^e State Key Laboratory of Reliability and Intelligence Electrical Equipment, National Engineering Research Center for Technological Innovation Method and Tool, and School of Mechanical Engineering, Hebei University of Technology, Tianjin 300401, China

Abstract

We report dense Na₃Zr₂Si₂PO₁₂ with an average grain size of 546 ± 58 nm and prepared by a facile method. The nano-grained Na₃Zr₂Si₂PO₁₂ exhibits an extremely high conductivity of 1.02 × 10⁻³ S cm⁻¹ and low interfacial resistance of 35 Ω cm² at 25 °C. Such processing facilitates the exploration of nanocrystalline conductors.

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Article information

DOI: https://doi.org/10.1039/D0CC07261C
Article type: Communication
Submitted: 03 Nov 2020
Accepted: 12 Mar 2021
First published: 12 Mar 2021

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Chem. Commun., 2021,57, 4023-4026

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A facile method for the synthesis of a sintering dense nano-grained Na₃Zr₂Si₂PO₁₂ Na⁺-ion solid-state electrolyte

G. Yang, Y. Zhai, J. Yao, S. Song, W. Tang, Z. Wen, L. Lu and N. Hu, Chem. Commun., 2021, 57, 4023 DOI: 10.1039/D0CC07261C

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