Issue 3, 2021
From the journal:

Chemical Communications

Palladium-catalyzed C–P cross-coupling of allenic alcohols with H-phosphonates leading to 2-phosphinoyl-1,3-butadienes†

Shanshan Hu,a   Wenyu Sun,a   Junhong Chen,b   Sipei Li,a   Runmin Zhao,b   Pengxiang Xu,*a   Yuxing Gao ORCID logo *a  and  Yufen Zhao ORCID logo a  

* Corresponding authors

a Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China
E-mail: gaoxingchem@xmu.edu.cn, xpengxiang@xmu.edu.cn

b Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China

Abstract

The first facile, efficient, atom-economical and regioselective palladium-catalyzed direct C–P cross-coupling of unprotected allenic alcohols with H-phosphonates for the one-pot synthesis of structurally diverse multisubstituted 2-phosphinoyl-1,3-butadienes was developed. This strategy would enrich the allene chemistry and afford new scaffolds to construct complex molecular skeletons.

Graphical abstract: Palladium-catalyzed C–P cross-coupling of allenic alcohols with H-phosphonates leading to 2-phosphinoyl-1,3-butadienes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0CC07022J
Article type
Communication
Submitted
22 Oct 2020
Accepted
23 Nov 2020
First published
24 Nov 2020

Chem. Commun., 2021,57, 339-342

Permissions

Request permissions

Palladium-catalyzed C–P cross-coupling of allenic alcohols with H-phosphonates leading to 2-phosphinoyl-1,3-butadienes

S. Hu, W. Sun, J. Chen, S. Li, R. Zhao, P. Xu, Y. Gao and Y. Zhao, Chem. Commun., 2021, 57, 339 DOI: 10.1039/D0CC07022J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements