Issue 2, 2021

Polymeric dimethylytterbium and the terminal methyl complex (TptBu,Me)Yb(CH3)(thf)

Abstract

Divalent ytterbium bis(trimethylsilyl)amides [Yb{N(SiMe3)2}2]2 and Yb[N(SiMe3)2]2(thf)2 react with purified methyllithium to amorphous dimethylytterbium [YbMe2]n. The characterisation was performed by 171Yb and 13C CP/MAS NMR spectroscopy as well as by conducting protonolysis reactions with HC5Me5 and HTptBu,Me, affording known (C5Me5)2Yb(OEt2) and new (TptBu,Me)Yb(CH3)(thf).

Graphical abstract: Polymeric dimethylytterbium and the terminal methyl complex (TptBu,Me)Yb(CH3)(thf)

Supplementary files

Article information

Article type
Communication
Submitted
20 Oct 2020
Accepted
24 Nov 2020
First published
24 Nov 2020

Chem. Commun., 2021,57, 243-246

Polymeric dimethylytterbium and the terminal methyl complex (TptBu,Me)Yb(CH3)(thf)

M. M. Katzenmayer, B. M. Wolf, A. Mortis, C. Maichle-Mössmer and R. Anwander, Chem. Commun., 2021, 57, 243 DOI: 10.1039/D0CC06981G

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