Issue 4, 2021
From the journal:

Chemical Communications

The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity†

Gabriel L. Murphy, ORCID logo *a   Yaxing Wang,b   Philip Kegler,a   Yumin Wang,b   Shuao Wang ORCID logo b  and  Evgeny V. Alekseev ORCID logo *a  

* Corresponding authors

a Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich 52428, Germany
E-mail: g.murphy@fz-juelich.de, e.alekseev@fz-juelich.de

b School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, 199 Ren’ai Road, Suzhou 215123, China

Abstract

Herein we report the first example of an actinide polyiodate compound, namely K4[(UO2)2(IO3)6(I4O11)]·(HIO3)4(H2O)6 (UPI-1), which was obtained from slow evaporation of nitric acid with a high I/U ratio. Spectroscopic measurements indicate that UPI-1 possesses X-ray luminescence properties applicable for X-ray scintillation and also exhibits modest protonic conduction.

Graphical abstract: The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity

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Article information

DOI
https://doi.org/10.1039/D0CC06835G
Article type
Communication
Submitted
13 Oct 2020
Accepted
24 Nov 2020
First published
17 Dec 2020

Chem. Commun., 2021,57, 496-499

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The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity

G. L. Murphy, Y. Wang, P. Kegler, Y. Wang, S. Wang and E. V. Alekseev, Chem. Commun., 2021, 57, 496 DOI: 10.1039/D0CC06835G

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