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Issue 39, 2020
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A high performance direct borohydride fuel cell using bipolar interfaces and noble metal-free Ni-based anodes

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Abstract

Due to its unmatched theoretical voltage of 2.18 V, a direct alkaline fuel cell using sodium borohydride solution at the anode and hydrogen peroxide at the cathode represents a promising power source for high energy density applications. However, its development faces several challenges. Here we demonstrate a BH4/H2O2 direct borohydride fuel cell (DBFC) with a platinum group metal (PGM)-free anode, which delivers an unprecedented combination of 2.0 V open-circuit voltage and a peak power density of 446 mW cm−2. This exceptionally high cell voltage is enabled by combining a pH-gradient-enabled microscale bipolar interface (PMBI), a Ni anode obtained by electrodeposition of Ni nanoparticles on a chemically etched Ni felt (eNFT), and a specially designed simple but efficient coating procedure to deposit anion-exchange ionomers on the anode surface. The PMBI efficiently separates the drastically disparate pH of the anolyte and the catholyte, the NiED/eNFT anode provides a high surface area for efficient electrocatalysis and open porosity for fast mass-transport, while the coating procedure allows preserving Ni in the metallic state, the latter being a prerequisite for high anode performance. This work details how such fully nickel-based anodes are obtained and demonstrates why their BOR activity and stability outperform those of PGM-based anodes.

Graphical abstract: A high performance direct borohydride fuel cell using bipolar interfaces and noble metal-free Ni-based anodes

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Supplementary files

Article information


Submitted
30 Jun 2020
Accepted
04 Sep 2020
First published
04 Sep 2020

J. Mater. Chem. A, 2020,8, 20543-20552
Article type
Paper

A high performance direct borohydride fuel cell using bipolar interfaces and noble metal-free Ni-based anodes

G. Braesch, Z. Wang, S. Sankarasubramanian, A. G. Oshchepkov, A. Bonnefont, E. R. Savinova, V. Ramani and M. Chatenet, J. Mater. Chem. A, 2020, 8, 20543
DOI: 10.1039/D0TA06405J

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