Pt single-atoms supported on nitrogen-doped carbon dots for highly efficient photocatalytic hydrogen generation

Abstract

Single-atom catalysis has become the most active new frontier in energy conversion applications due to its remarkable catalytic activity and low material consumption. However, the issue of atom aggregation during the synthesis process or catalytic reaction must be overcome. In this work, we have developed a one-step photo-deposition process to fabricate Pt single-atom catalysts (SACs) on nitrogen doped carbon dots (NCDs). The Pt–NCDs were then hybridized with TiO₂ to achieve high hydrogen generation activity and to understand the fundamentals at the Pt/NCD/TiO₂ interface. The synergistic effect of Pt SAC and NCDs with maximized atomic efficiency of Pt and improved charge transfer capability provides a new strategy to rationally design a multi-scale photocatalyst structure to achieve high H₂ evolution efficiency. The facile synthesis process also holds great potential for various applications such as electrocatalysis, heterogeneous catalysis and drug delivery, providing a promising way to reduce the high cost of noble metals.