Issue 43, 2020

Dynamics of progressive pore clogging by colloidal aggregates

Abstract

The flow of a suspension through a bottleneck often leads to its obstruction. Such a continuous flow to clogging transition has been well characterized when the constriction width to particle size ratio, W/D, is smaller than 3–4. In such cases, the constriction is either blocked by a single particle that is larger than the constriction width (W/D < 1), or there is an arch formed by several particles that try to enter it together (2 < W/D < 4). For larger W/D ratios, 4 < W/D < 10, the blockage of the constriction is presumed to be due to the successive accumulations of particles. Such a clogging mechanism may also apply to wider pores. The dynamics of this progressive obstruction remains largely unexplored since it is difficult to see through the forming clog and we still do not know how particles accumulate inside the constriction. In this paper, we use particle tracking and image analysis to study the clogging of a constriction/pore by stable colloidal particles. These techniques allow us to determine the shape and the size of all the objects, be they single particles or aggregates, captured inside the pore. We show that even with the rather monodisperse colloidal suspension we used individual particles cannot clog a pore alone. These individual particles can only partially cover the pore surface whilst it is the very small fraction of aggregates present in the suspension that can pile up and clog the pore. We analyzed the dynamics of aggregate motion up to the point of capture within the pore, which helps us to elucidate why the probability of aggregate capture inside the pore is high.

Graphical abstract: Dynamics of progressive pore clogging by colloidal aggregates

Supplementary files

Article information

Article type
Paper
Submitted
04 Aug 2020
Accepted
28 Sep 2020
First published
30 Sep 2020

Soft Matter, 2020,16, 9899-9907

Dynamics of progressive pore clogging by colloidal aggregates

N. Delouche, A. B. Schofield and H. Tabuteau, Soft Matter, 2020, 16, 9899 DOI: 10.1039/D0SM01403F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements