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Palladium-catalyzed direct asymmetric C–H bond functionalization enabled by the directing group strategy

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Abstract

In the past decade, selective C–C and C-heteroatom bond construction through palladium-catalyzed direct C–H bond functionalization has been extensively studied by employing a variety of directing groups. Within this category, direct asymmetric C(sp2)–H and C(sp3)–H activation for the construction of highly enantiomerically enriched skeletons still progressed at a slow pace. This minireview briefly introduces the major advances in the field for palladium-catalyzed direct asymmetric C–H bond functionalization via the directing group strategy.

Graphical abstract: Palladium-catalyzed direct asymmetric C–H bond functionalization enabled by the directing group strategy

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Article information


Submitted
31 May 2020
Accepted
08 Jul 2020
First published
09 Jul 2020

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2020, Advance Article
Article type
Minireview

Palladium-catalyzed direct asymmetric C–H bond functionalization enabled by the directing group strategy

K. Yang, M. Song, H. Liu and H. Ge, Chem. Sci., 2020, Advance Article , DOI: 10.1039/D0SC03052J

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