Degradation of norfloxacin by copper-doped Bi2WO6-induced sulfate radical-based visible light-Fenton reaction

Abstract

In this work, a series of Cu(II)-doped Bi₂WO₆ nanomaterials with good photo-response properties were facile synthesized and used to obtain efficient peroxymonosulfate (PMS) activation activity for norfloxacin (NOF) removal under visible LED light irradiation. It was found that Cu–Bi₂WO₆ presents superior catalytic performance for NOF degradation in comparison with pristine Bi₂WO₆, attributed to the partial substitution of Bi³⁺ by Cu ions. Moreover, the effects of experimental conditions were carefully investigated, including PMS concentration, catalyst dosage and initial pH, and the experimental data fitted well with the pseudo-first-order model. Experimental results implied that there was a synergic effect of visible LED light energy and the sulfate radical (SR)-Fenton reaction. Additionally, the 5Cu–Bi₂WO₆ nanomaterial presented the best degradation efficiency of 89.27% and exhibited high NOF degradation in 5 cycles with limited Cu leaching. Furthermore, EPR and radical quenching experiments were performed to identify the reactive oxygen species presented in the SR-photo-Fenton reaction. Finally, the major degradation intermediates of NOF were detected, and a possible degradation pathway was given. Thus, a mechanism of the significant photocatalytic activity enhancement by copper doping of the Bi₂WO₆ catalyst was proposed.