The synthesis of polyaspartic acid derivative PASP-Im and investigation of its scale inhibition performance and mechanism in industrial circulating water

Abstract

A polyaspartic acid derivative (PASP-Im) as a novel scale inhibitor was synthesized by a simple green synthesis route with polysuccinimide and iminodiacetic acid as the starting materials. The as-synthesized PASP-Im was characterized via nuclear magnetic resonance spectroscopy (¹H-NMR) and Fourier transform infrared spectrometry (FT-IR), and its scale inhibition performance was evaluated by a static scale inhibition method. Moreover, scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and density functional theory computational studies were conducted to explore the scale inhibition mechanism of PASP-Im. The findings indicate that the as-synthesized PASP-Im exhibits better antiscale performance against the CaCO₃ deposits than the unmodified PASP because of the introduction of iminodiacetic acid group. It also can change the crystallization path of calcium carbonate from stable calcite to vaterite that is dispersible in water, thereby resulting in great changes in the morphology of the CaCO₃ scale. Furthermore, the O and N atoms in the negatively charged functional groups (such as –NH₂ and –COOH) of PASP-Im can interact with calcium ions to block the active growth point of CaCO₃ crystals, which also accounts for the excellent antiscale performance of PASP-Im. With new insights into the synergy between the functional groups of the antiscale molecule and scale-forming ions, this approach would be helpful towards the development of novel high-performance anti-scaling macromolecules.