Issue 56, 2020

Recent advances in liquid hydrosilane-mediated catalytic N-formylation of amines with CO2

Abstract

Carbon dioxide is an ideal raw material for the synthesis of complex organic compounds because of its rich, non-toxic, and good physical properties. It is of great significance to transform CO2 into valuable fine chemicals and develop a green sustainable cycle of carbon surplus. Based on hydrosilane as a reducing agent, this work summarizes the recent applications of reductive amidation of CO2 using different catalysts such as organocatalysts, ionic liquids (ILs), salts, transition metal complexes, and solvents. The main factors affecting the reductive amidation of CO2 and the possible reaction mechanism are discussed. Moreover, the future orientation and catalytic systems of the formylation of amines with CO2 and hydrosilane are prospected.

Graphical abstract: Recent advances in liquid hydrosilane-mediated catalytic N-formylation of amines with CO2

Article information

Article type
Review Article
Submitted
05 Jul 2020
Accepted
08 Sep 2020
First published
14 Sep 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 33972-34005

Recent advances in liquid hydrosilane-mediated catalytic N-formylation of amines with CO2

Z. Li, Z. Yu, X. Luo, C. Li, H. Wu, W. Zhao, H. Li and S. Yang, RSC Adv., 2020, 10, 33972 DOI: 10.1039/D0RA05858K

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