Highly flexible reduced graphene oxide@polypyrrole–polyethylene glycol foam for supercapacitors

Abstract

A flexible and free-standing 3D reduced graphene oxide@polypyrrole–polyethylene glycol (RGO@PPy–PEG) foam was developed for wearable supercapacitors. The device was fabricated sequentially, beginning with the electrodeposition of PPy in the presence of a PEG–borate on a sacrificial Ni foam template, followed by a subsequent GO wrapping and chemical reduction process. The 3D RGO@PPy–PEG foam electrode showed excellent electrochemical properties with a large specific capacitance of 415 F g⁻¹ and excellent long-term stability (96% capacitance retention after 8000 charge–discharge cycles) in a three electrode configuration. An assembled (two-electrode configuration) symmetric supercapacitor using RGO@PPy–PEG electrodes exhibited a remarkable specific capacitance of 1019 mF cm⁻² at 2 mV s⁻¹ and 95% capacitance retention over 4000 cycles. The device exhibits extraordinary mechanical flexibility and showed negligable capacitance loss during or after 1000 bending cycles, highlighting its great potential in wearable energy devices.