Temperature–humidity dual regulation of a single-core–double-shell microcapsule fabricated by electrostatic-assembly and chemical precipitation

Abstract

Humidity and temperature control materials have attracted increasing attention due to their energy saving and intelligent regulation of human comfort in the field of interior building and clothing. Phase change microcapsules have been widely used, however, most of which focus on temperature regulation without humidity control. In this work, we report a novel temperature–humidity dual regulation microcapsule with single-core–double-shell structure. FT-IR and XRD measurements confirmed that the shell materials were successfully fabricated on the paraffin core via electrostatic-assembly and the subsequent chemical precipitation method. SEM, TEM and optical microscope photos showed that the microcapsules were spherical morphology with layer-by-layer shells at a diameter around 2–5 μm. The SiO₂ shell was aggregated from nano-sized particles and formed a loose and porous micro-structure, supported by the result of N₂ adsorption–desorption isotherms. In addition, the synergistic effect of hydrophilic and porous loose (chitosan/GO/chitosan)–SiO₂ double shells endowed the microcapsules with humidity regulation. The constructed microcapsules showed temperature regulation behavior due to its phase change performance of paraffin and good thermal durability after 10 thermal cycles. They also showed stable humidity regulation performance after repeated adsorption/desorption. The simulation experiments of temperature and humidity regulation indicated that the microcapsule could keep the temperature and humidity in a stable range. The as-prepared microcapsules have outstanding temperature and humidity regulation properties, showing an application prospects in energy-saving fields.