Removal of reactive brilliant red X-3B by a weak magnetic field enhanced Fenton-like system with zero-valent iron

Abstract

The effect of a weak magnetic field (WMF) on the removal of reactive brilliant red X-3B (X-3B) by zero-valent iron (ZVI)/H₂O₂ was studied. The optimum conditions for the removal of X-3B by the ZVI/H₂O₂/WMF system were as follows: pH = 4.0, X-3B was 50 mg L⁻¹, H₂O₂ was 8 mM, and ZVI with particle size of 20 μm was 0.5 g L⁻¹. The X-3B decolorization rate could reach 99.41% in 10 minutes. The superposed WMF increased the working pH of ZVI from 3.0 to 4.0. The main part of ZVI/H₂O₂ removal kinetics of X-3B followed the zero order rate law. In this study, the removal effect of X-3B by pre-magnetization ZVI was not as good as that of real-time magnetization, but it was better than the removal of X-3B by the ZVI/H₂O₂ system. The ZVI/H₂O₂/WMF system still had the ability to remove X-3B after 4 consecutive cycles. The use of WMF improved the removal of X-3B by ZVI/H₂O₂ mainly due to the corrosion of ZVI. Under acidic conditions, WMF enhanced the activity of ZVI, which promoted the efficiency of the Fenton reaction. The use of WMF to enhance the ZVI/H₂O₂ removal X-3B was a promising and environmental friendly process because it did not require additional energy and expensive reagents and did not cause secondary pollution.