Issue 35, 2020, Issue in Progress

Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols

Abstract

A one-pot, clean and green procedure is described for the syntheses of new azocine derivatives via addition reactions of enaminones with acenaphthoquinone followed by periodic acid-mediated oxidative cleavages of the corresponding vicinal diols. Various derivatives of azocine were prepared and well characterized. The excellent yields, simple synthesis procedure, lack of a need to carry out any tedious work-up and column chromatography, metal-free catalysis, and mild reaction conditions are important features of this protocol.

Graphical abstract: Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols

Supplementary files

Article information

Article type
Paper
Submitted
28 Mar 2020
Accepted
22 May 2020
First published
29 May 2020
This article is Open Access
Creative Commons BY license

RSC Adv., 2020,10, 20552-20557

Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols

S. H. Mousavi, M. R. Mohammadizadeh, S. Arimitsu, D. Saberi, S. Poorsadeghi and K. Genta, RSC Adv., 2020, 10, 20552 DOI: 10.1039/D0RA02852E

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