A one-dimensional infinite silver alkynyl assembly [Ag8(CCtBu)5(CF3COO)3(CH3CN)]n: synthesis, crystal structure and properties

Ju-Feng Shi; Zhi-Jin Chen; Liu-Jie Zhang; Kun Zhou; Jiu-Yu Ji; Yan-Feng Bi

doi:10.1039/D0RA01703E

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A one-dimensional infinite silver alkynyl assembly [Ag₈(CC^tBu)₅(CF₃COO)₃(CH₃CN)]_n: synthesis, crystal structure and properties†

Ju-Feng Shi,^a Zhi-Jin Chen,^a Liu-Jie Zhang,

^a Kun Zhou,

*^a Jiu-Yu Ji

^a and Yan-Feng Bi

*^a

Author affiliations

* Corresponding authors

^a School of Chemistry and Materials Science, Liaoning Shihua University, Fushun, Liaoning 113001, China
E-mail: zhouk800@aliyun.com, biyanfeng@lnpu.edu.cn

Abstract

A high-yield silver alkynyl assembly [Ag₈(C [triple bond, length as m-dash] C^tBu)₅(CF₃COO)₃(CH₃CN)]_n (1) constructed from [AgCC^tBu]_n ligand, CF₃COOAg and CH₃CN auxiliary ligands with a one-dimensional infinite chain structure has been obtained in one pot. Compound 1 has been well-defined and characterized. The photocurrent properties and the temperature-sensitive luminescent properties of 1 have been investigated.

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Article information

DOI: https://doi.org/10.1039/D0RA01703E
Article type: Paper
Submitted: 22 Feb 2020
Accepted: 07 Apr 2020
First published: 22 Apr 2020
This article is Open Access

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RSC Adv., 2020,10, 16045-16049

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A one-dimensional infinite silver alkynyl assembly [Ag₈(CC^tBu)₅(CF₃COO)₃(CH₃CN)]_n: synthesis, crystal structure and properties

J. Shi, Z. Chen, L. Zhang, K. Zhou, J. Ji and Y. Bi, RSC Adv., 2020, 10, 16045 DOI: 10.1039/D0RA01703E

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