A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO2

Maryam Abassian; Rahele Zhiani; Alireza Motavalizadehkakhky; Hossein Eshghi; Jamshid Mehrzad

doi:10.1039/D0RA01696A

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A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO₂

Maryam Abassian,^a Rahele Zhiani,

*^b Alireza Motavalizadehkakhky,

*^a Hossein Eshghi

^c and Jamshid Mehrzad^d

Author affiliations

* Corresponding authors

^a Department of Chemistry, Faculty of Science, Islamic Azad University, Neyshabur Branch, Neyshabur, Iran
E-mail: amotavalizadeh@yahoo.com

^b New Materials Technology and Processing Research Center, Department of Chemistry, Islamic Azad University, Neyshabur Branch, Neyshabur, Iran
E-mail: R_zhiani2006@yahoo.com

^c Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashhad, Iran

^d Department of Biochemistry, Faculty of Science, Islamic Azad University, Neyshabur Branch, Neyshabur, Iran

Abstract

We studied the potential application of an efficient, reusable, and easily recoverable catalyst of dendritic fibrous nanosilica (DFNS)-supported platinum(II) complexes (DFNS/Pt(II) NPs) to form cyclic carbonates in the presence of epoxides by converting carbon dioxide. Cyclic carbonates from epoxides and carbon dioxide is proposed as the most appropriate way to synthesis this C1 building block. We performed FE-SEM, TEM, TGA, BET, VSM, and ICP-MS to thoroughly characterize DFNS/Pt(II) NPs.

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Article information

DOI: https://doi.org/10.1039/D0RA01696A
Article type: Paper
Submitted: 21 Feb 2020
Accepted: 20 Mar 2020
First published: 16 Apr 2020
This article is Open Access

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RSC Adv., 2020,10, 15044-15051

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A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO₂

M. Abassian, R. Zhiani, A. Motavalizadehkakhky, H. Eshghi and J. Mehrzad, RSC Adv., 2020, 10, 15044 DOI: 10.1039/D0RA01696A

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A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO₂

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A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO₂

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