Poly(3,4-ethylenedioxyselenophene): effect of solvent and electrolyte on electrodeposition, optoelectronic and electrochromic properties

Abstract

In this article, we report the effect of electropolymerization conditions such as solvent and supporting electrolyte on the redox, optoelectronic and electrochromic properties of PEDOS. Monomer EDOS was synthesized by new and simple route and its electropolymerization was investigated by employing six different combinations of solvent–electrolyte namely TBAClO₄/MeCN, TBAPF₆/MeCN, TBABF₄/MeCN, TBAClO₄/PC, TBAPF₆/PC and TBABF₄/PC. Further, the electrochemical, spectroelectrochemistry, morphology and electrochromic properties of resultant PEDOS films were systematically studied. A pronounced effect of both solvent and supporting electrolyte on the electropolymerization, redox, optoelectronic and electrochromic properties on PEDOS film is noted. Among all solvent–electrolyte systems, MeCN and TBAClO₄ were found to be the most suitable medium for electropolymerization of EDOS. Further, PEDOS films prepared in PC showed red shifted absorption maxima, narrow absorption peaks in UV-vis-NIR spectra, slightly more smooth morphologies, and high optical contrasts ratio and coloration efficiency in comparison to MeCN. PEDOS films prepared in TBABF₄/PC exhibited longer λ_max (670 nm), smooth morphology, and the highest optical contrasts ratio (44.6%) and coloration efficiency (141.8 cm² C⁻¹) compared to the other solvent–electrolyte medium.