Aggregation-induced enhanced emission-type cruciform luminophore constructed by carbazole exhibiting mechanical force-induced luminescent enhancement and chromism

Abstract

One D–A type cruciform luminophore MDCS-BC based on carbazole has been prepared. We observed that this compound exhibits unique intramolecular charge-transfer (ICT) and typical aggregation-induced enhanced emission (AIEE) properties with the solid-state luminescence efficiency of 0.184. Moreover, this luminophore shows a significant stimuli-induced emission enhancement and chromism effect with good reversibility. Upon grinding, the fluorescence color of the as-prepared samples can change from blue (454 nm) to green (504 nm). What is unexpected is that the fluorescence efficiency of the initial powder is dramatically increased from 0.184 to 0.424 upon grinding. The results of PXRD, DSC and spectral properties studies show that the mechanical force-induced luminescence enhancement and chromism behavior of MDCS-BC originates from the transition between crystal and amorphous morphology, and the large red-shift and the emission enhancement inducing by grinding may be attributed to the planarization of the molecular conformation and subsequent planar ICT process.