Self-healing composite hydrogel with antibacterial and reversible restorability conductive properties

Abstract

Self-healable PAA/PPy–Fe composite hydrogels have been simply synthesized in one step and utilized for antibacterial and electrical conductivity application. The network of hydrogel is composed of polyacrylic acid (PAA) and Fe³⁺ ions with interlacing of the second polymeric chain of polypyrrole (PPy). In this study, ammonium persulfate (APS) was utilized to initiate the polymerization of both acrylic acid and pyrrole. Such hydrogels exhibited good mechanical properties and remarkable self-healing efficiency as well. The self-healing ability of the hydrogels was facilitated by ionic interaction between carboxylic anion groups (COO–) from polyacrylic acid (PAA) and Fe³⁺ ions. Moreover, the antibacterial activity of the composite hydrogels was examined on Escherichia coli via the disk diffusion method and the zone of inhibition was obtained in the range of 1.26–1.56 cm after incubation for 12 h. In addition, demonstration of the PAA/PPy–Fe composite hydrogels in electrical conductivity applications was performed in which the composite hydrogel was set up in an electrical circuit consisting of an LED and powered by 3 V batteries. The results showed that the electricity could light-up the LED through the PAA/PPy–Fe composite hydrogels and possessed reversible restorability, as indicated by the healed hydrogel consistently lighting-up the LED in the electrical circuit.