Synthesis of poly(ionic liquid) for trifunctional epoxy resin with simultaneously enhancing the toughness, thermal and dielectric performances

Abstract

Poly(ionic liquid) (PIL), integrating the characteristics of both polymers and ionic liquid, is synthesized and employed to modify diglycidyl-4,5-epoxy-cyclohexane-1,2-dicarboxylate (TDE-85). With the addition of PIL, the fracture toughness, and thermal and dielectric performances of TDE-85 were discovered to be simultaneously improved, meanwhile the tensile modulus and strength is increased. Upon an optimal loading of 3 wt% PIL, the critical stress intensity factor (K_IC), tensile modulus and strength are raised by 92.9%, 13.3% and 10.7%, respectively. Multi-toughening mechanisms due to spherical domains of PIL formed in TDE-85 during curing are responsible for the improved toughness. Moreover, the dielectric and thermal properties of TDE-85 are also enhanced by adding PIL. With the optimal addition of 5 wt% PIL, the dielectric constant of the composites is enhanced by 62.5%, the glass transition temperature is increased by 16.58 °C and the residual weight of carbon is increased by 59%.