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Issue 17, 2020
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Photoinduced strategies towards strained molecules

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Abstract

New photoinduced strategies towards radical reactions of strained molecules such as [1.1.1]propellane and bicyclo[1.1.0]butanes by photoredox or metallaphotoredox catalysis have recently been disclosed. Such strategies enable the controllable construction of 1,3-difunctionalized bicyclo[1.1.1]pentanes, cyclobutanes, and drug-like analogues, and offer new opportunities for reaction design of [1.1.1]propellane and other strained molecules.

Graphical abstract: Photoinduced strategies towards strained molecules

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Article information


Submitted
11 Jun 2020
Accepted
21 Jul 2020
First published
22 Jul 2020

Org. Chem. Front., 2020,7, 2531-2537
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Photoinduced strategies towards strained molecules

M. M. D. Pramanik, H. Qian, W. Xiao and J. Chen, Org. Chem. Front., 2020, 7, 2531
DOI: 10.1039/D0QO00460J

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