Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 10, 2020
Previous Article Next Article

Pd/light-induced alkyl–alkenyl coupling reaction between unactivated alkyl iodides and alkenylboronic acids

Author affiliations

Abstract

Alkyl–alkenyl coupling reaction between unactivated alkyl iodides and 2-arylalkenylboronic acids utilizing a Pd/light combined system was studied. This reaction provided 2-alkylarylalkenes in good yields. It is proposed that in this reaction alkyl radicals are formed by SET from a Pd catalyst to alkyl iodides, which then undergo addition reactions to form C–C double bonds of alkenyl boronic acids and the subsequent β-fragmentation of boronyl radicals leads to the formation of alkyl-substituted arylalkenes.

Graphical abstract: Pd/light-induced alkyl–alkenyl coupling reaction between unactivated alkyl iodides and alkenylboronic acids

Back to tab navigation

Supplementary files

Article information


Submitted
12 Mar 2020
Accepted
13 Apr 2020
First published
16 Apr 2020

Org. Chem. Front., 2020,7, 1266-1270
Article type
Research Article

Pd/light-induced alkyl–alkenyl coupling reaction between unactivated alkyl iodides and alkenylboronic acids

H. Huang, Y. Wang, Y. Wu and I. Ryu, Org. Chem. Front., 2020, 7, 1266
DOI: 10.1039/D0QO00318B

Social activity

Search articles by author

Spotlight

Advertisements