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Issue 1, 2020
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Solid-state-stabilization of molecular vanadium oxides for reversible electrochemical charge storage

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Abstract

Molecular vanadium oxides are promising active materials for cathodes in lithium and post-lithium batteries due to their high redox activity, low molecular weight and facile tuneability. However, a major challenge for this application is the transformation of the molecular clusters into solid-state oxides under typical electrode fabrication conditions. Here, we report a molecular crystal engineering approach for the stabilization of molecular vanadium oxides in the crystal lattice, enabling initial studies on reversible electron storage in a lithium ion battery test cell.

Graphical abstract: Solid-state-stabilization of molecular vanadium oxides for reversible electrochemical charge storage

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Submitted
24 Sep 2019
Accepted
23 Oct 2019
First published
24 Oct 2019

Inorg. Chem. Front., 2020,7, 134-139
Article type
Research Article

Solid-state-stabilization of molecular vanadium oxides for reversible electrochemical charge storage

S. Greiner, M. H. Anjass, M. Fichtner and C. Streb, Inorg. Chem. Front., 2020, 7, 134
DOI: 10.1039/C9QI01229J

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