Structures and Properties of Side-Chain Liquid Crystalline Polynorbornenes Containing Amide Group: Hydrogen Bonding Interaction and Spacer Length Effect.
To Investigate the structure-property relationship of side-chain liquid crystalline (LC) polymer with specific interactions, we synthesized a series of polynorbornene derivatives bearing benzanilide side-chains (denoted as P8-n, where n represents the number of methylene units in the spacer, and the number 8 indicates the side-chain tail of octyl). For comparison, a reference polynorbornene derivative (denoted as P8-6-E) was also synthesized by replacing amide group in the rod-like mesogen with ester group. It is found that with polynorbornene main-chain the samples can exhibit rich LC behaviors, different from other benzanilide-containing polymers. P8-2 and P8-4 form a bilayer smectic C (SmC2) phase. On the other hand, with longer spacers, the molecules of P8-8 and P8-10 can pack into a highly ordered structure (denoted as X1). The X1 phase has an orthorhombic lattice with the side- and main-chain along the c- and b-axis, wherein the side-chains are interdigitated packed with some features of crystal E (CrE) structure. For P8-6, some bilayer CrE domains may coexist with X1, resulting a mixed phase of X1/E2. It is unveiled that the amide group at the center of benzanilide always tends to form hydrogen bonds, leading to the unique molecular packing of P8-ns which is dependent on the size matching between the spacer and tail. Moreover, weakening the hydrogen bonds in P8-ns (n ≥ 8) could induce the phase transition from X1 to X1/E2. Compared with the rather soft and ductile P8-6-E with a smectic B phase, P8-ns show much higher Young’s moduli because of the existence of lateral hydrogen bonds. While those with the X1 phase are brittle, the P8-ns with SmC2 structure exhibit better overall mechanical properties, rendering the breaking strain of ~450%.