Intermolecular fluoroamination of allenes towards substituted vinyl fluorides

Vibha Tiwari; Jacob T. Bingham; Shubham Vyas; Anand Singh

doi:10.1039/D0OB01697G

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Intermolecular fluoroamination of allenes towards substituted vinyl fluorides†

Vibha Tiwari,^a Jacob T. Bingham,^b Shubham Vyas*^b and Anand Singh

*^a

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* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, U.P., India
E-mail: anands@iitk.ac.in

^b Department of Chemistry, Colorado School of Mines, Golden, Colorado 80401, USA

Abstract

A synthetic method towards fluorinated allylamines using allene precursors is reported. A variety of heterocyclic amines were employed as nucleophiles in a Selectfluor promoted intermolecular fluoroamination reaction. This strategy provides a novel synthetic route to access vinyl fluorides with a vicinal amine moiety.

This article is part of the themed collection: Synthetic methodology in OBC

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DOI: https://doi.org/10.1039/D0OB01697G
Article type: Communication
Submitted: 16 Aug 2020
Accepted: 30 Oct 2020
First published: 03 Nov 2020

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Org. Biomol. Chem., 2020,18, 9044-9049

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Intermolecular fluoroamination of allenes towards substituted vinyl fluorides

V. Tiwari, J. T. Bingham, S. Vyas and A. Singh, Org. Biomol. Chem., 2020, 18, 9044 DOI: 10.1039/D0OB01697G

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Organic & Biomolecular Chemistry

Intermolecular fluoroamination of allenes towards substituted vinyl fluorides†

Abstract

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Intermolecular fluoroamination of allenes towards substituted vinyl fluorides

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