Issue 33, 2020
From the journal:

Organic & Biomolecular Chemistry

An efficient imidation of thioethers with nitrene in water†

Tao Feng,a   Zhihui Tang,a   Xiaoli Luoa  and  Junming Mo ORCID logo *a  

* Corresponding authors

a Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530006, China
E-mail: moandli@163.com

Abstract

The first imidation of thioethers with free nitrene in water was realized. N-Cbz sulfilimines are formed via imidation of thioethers with free nitrene generated from α elimination of nosyloxycarbamates. In this work, water is successfully applied as solvent for free nitrene, and transition metal catalyst is not needed.

Graphical abstract: An efficient imidation of thioethers with nitrene in water

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Article information

DOI
https://doi.org/10.1039/D0OB01539C
Article type
Communication
Submitted
25 Jul 2020
Accepted
10 Aug 2020
First published
10 Aug 2020

Org. Biomol. Chem., 2020,18, 6497-6501

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An efficient imidation of thioethers with nitrene in water

T. Feng, Z. Tang, X. Luo and J. Mo, Org. Biomol. Chem., 2020, 18, 6497 DOI: 10.1039/D0OB01539C

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