Amplifying the excited state chirality through self-assembly and subsequent enhancement via plasmonic silver nanowires

Abstract

The development of circularly polarized luminescent materials with a large luminescence dissymmetry factor (g_lum) is continuing to be a big challenge. Here, we present a general approach for amplifying circular polarization of circularly polarized luminescence (CPL) through intergrating molecular self-assembly and surface plasmon resonance (SPR). Molecular self-assembly could amplify the CPL performance. Subsequently, the composites built of nanoassemblies and achiral silver nanowires (AgNWs) show intense CPL activity with an amplified g_lum value. By applying an external magnetic field, the CPL activity of the nanoassemblies/AgNWs composites has been significantly enhanced, confirming a plasmon-enhanced circular polarization. Our design strategy based on SPR-enhanced circular polarization of the chiral emissive systems suggests that combining plasmonic nanomaterials with chiral organic materials could aid in the development of novel CPL active nanomaterials.