The preparation of hollow Fe3O4/Pd@C NCs to stabilize subminiature Pd nanoparticles for the reduction of 4-nitrophenol

Abstract

N-Doped hollow Fe₃O₄/Pd@C nanocontainer (NC) composites, involving the loading of magnetic Fe₃O₄ and subminiature noble metal Pd nanoparticles (NPs), were prepared. The synthetic process involves the decomposition of Fe₃O₄/Pd²⁺@ZIF-8 and the polymerization of dopamine simultaneously via a “Chelation Competition Induced Polymerization” process, forming hollow polymer NCs. Then, they were carbonized into Fe₃O₄/Pd@C NCs. The structure and composition of the as-prepared nanocontainers were characterized. The catalytic performance of the Fe₃O₄/Pd@C NC composites was studied by the reduction of 4-nitrophenol with NaBH₄ as a reducing agent. The reaction rate constant was calculated according to the pseudo-first-order reaction equation. It was found that subminiature Pd NPs were obtained, and the coordination interaction between Pd and N in PDA prevented Pd NPs from aggregating during high-temperature calcination, resulting in a high k value. Besides the good catalytic properties, high stability of Fe₃O₄/Pd@C NCs was also confirmed.