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Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

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Abstract

A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na and 2-butoxyethyl ether represents the key promoting factor for the reaction.

Graphical abstract: Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

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Article information


Submitted
03 Aug 2020
Accepted
26 Nov 2020
First published
26 Nov 2020

Green Chem., 2021, Advance Article
Article type
Paper

Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

K. Liu, Z. Wang, L. Lu, J. Chen, F. Zeng, Y. Lin, Z. Cao, X. Yu and W. He, Green Chem., 2021, Advance Article , DOI: 10.1039/D0GC02663H

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