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Enhanced capacitive deionization of saline water using N-doped rod-like porous carbon derived from dual-ligand metal-organic frameworks

Abstract

Capacitive deionization (CDI) is a forward-looking technology that removes ions from brine due to its low energy consumption, low cost and prevention of secondary pollution. Removal capacity is still an issue for the CDI technology. It is quite urgent to design high performance CDI electrode material with reasonable porous structure, excellent conductivity and hydrophilic surface. Herein, we originally designed nitrogen-doped rod-like porous carbon derived from dual-ligand metal-organic frameworks (MOFs), in which two ligands, namely 1, 4-benzenedicarbocylic acid and triethylenediamine, to coordinate with zinc (Zn), respectively. The 1, 4-benzenedicarbocylic acid can be used as a pore-forming agent to increase the specific surface area of carbon material, and the triethylenediamine is used as nitrogen doping source to increase the hydrophilicity and conductivity of carbon material. By adjusting the ratio of two ligands, the optimal specific surface area and nitrogen doping for carbon material is obtained, thereby achieving the highest removal capacity for capacitive deionization of brine. The obtained carbon materials possess a hierarchical porous structure with moderate nitrogen doping. The large specific surface area of the electrode materials delivers many adsorption sites for adsorption of salt ions. The hierarchically porous structure provides a rapid transport channel of salt ions, and high-level N doping enhances conductivity and hydrophilicity for carbon materials to some extent. More importantly, the salt removal capacity of the electrodes is as high as 24.17 mg g-1 at 1.2 V in 500 mg L-1 NaCl aqueous solution. Hence, the moderate nitrogen doping porous carbon materials derived from dual-ligand MOFs is potential electrode material for CDI application. Such results open up a new method for preparation high performance electrodes to remove ions from saline water.

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Supplementary files

Article information


Submitted
25 Oct 2019
Accepted
13 Jan 2020
First published
13 Jan 2020

Environ. Sci.: Nano, 2020, Accepted Manuscript
Article type
Paper

Enhanced capacitive deionization of saline water using N-doped rod-like porous carbon derived from dual-ligand metal-organic frameworks

J. Zhang, T. Yan, J. Fang, J. Shen, L. Shi and D. Zhang, Environ. Sci.: Nano, 2020, Accepted Manuscript , DOI: 10.1039/C9EN01216H

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