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Issue 48, 2020
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A valence tautomeric cobalt–dioxolene complex with an anchoring group for prospective chemical grafting to metal oxides

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Abstract

Here, we synthesized a valence tautomeric cobalt–dioxolene complex featuring a protected anchoring group. At room temperature, the complex reveals a nearly pure low-spin-Co(III)-catecholate state in the solid state, but a nearly pure high-spin-Co(II)-semiquinonate state in toluene solution. Thermal switchability of the complex in solution and in the solid state is investigated.

Graphical abstract: A valence tautomeric cobalt–dioxolene complex with an anchoring group for prospective chemical grafting to metal oxides

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Article information


Submitted
02 Nov 2020
Accepted
27 Nov 2020
First published
27 Nov 2020

Dalton Trans., 2020,49, 17532-17536
Article type
Communication

A valence tautomeric cobalt–dioxolene complex with an anchoring group for prospective chemical grafting to metal oxides

M. Mörtel, M. Seller, F. W. Heinemann and M. M. Khusniyarov, Dalton Trans., 2020, 49, 17532
DOI: 10.1039/D0DT03771K

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