Amidinate based indium(III) monohalides and β-diketiminate stabilized In(II)–In(II) bond: synthesis, crystal structure, and computational study

Samya Banerjee; Sayan Dutta; Samir Kumar Sarkar; Nico Graw; Regine Herbst-Irmer; Debasis Koley; Dietmar Stalke; Herbert W. Roesky

doi:10.1039/D0DT03161E

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Amidinate based indium(iii) monohalides and β-diketiminate stabilized In(ii)–In(ii) bond: synthesis, crystal structure, and computational study†

Samya Banerjee,

^a Sayan Dutta,

^b Samir Kumar Sarkar,

^a Nico Graw,

^a Regine Herbst-Irmer,

^a Debasis Koley,

*^b Dietmar Stalke

*^a and Herbert W. Roesky

*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, Georg-August-Universität Göttingen, 37077 Göttingen, Germany
E-mail: hroesky@gwdg.de, dstalke@chemie.uni-goettingen.de

^b Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur 741 246, India
E-mail: koley@iiserkol.ac.in

Abstract

Synthesis and bonding aspects of mononuclear bis-amidinate indium(III) monohalides L₂InX (1–3), where L = PhC(N^tBu)₂; X is F (1), Br (2) or I (3) and β-diketiminate (NacNac) stabilized In(II) dimer (^MesNacNac)₂In₂Br₂ (4) with In–In bond are reported along with the single-crystal X-ray structures of 2–4.

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DOI: https://doi.org/10.1039/D0DT03161E
Article type: Paper
Submitted: 09 Sep 2020
Accepted: 30 Sep 2020
First published: 01 Oct 2020
This article is Open Access

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Dalton Trans., 2020,49, 14231-14236

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Amidinate based indium(III) monohalides and β-diketiminate stabilized In(II)–In(II) bond: synthesis, crystal structure, and computational study

S. Banerjee, S. Dutta, S. K. Sarkar, N. Graw, R. Herbst-Irmer, D. Koley, D. Stalke and H. W. Roesky, Dalton Trans., 2020, 49, 14231 DOI: 10.1039/D0DT03161E

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Dalton Transactions

Amidinate based indium(iii) monohalides and β-diketiminate stabilized In(ii)–In(ii) bond: synthesis, crystal structure, and computational study†

Abstract

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Amidinate based indium(III) monohalides and β-diketiminate stabilized In(II)–In(II) bond: synthesis, crystal structure, and computational study

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