Amidinate based indium(iii) monohalides and β-diketiminate stabilized In(ii)–In(ii) bond: synthesis, crystal structure, and computational study†
Abstract
Synthesis and bonding aspects of mononuclear bis-amidinate indium(III) monohalides L2InX (1–3), where L = PhC(NtBu)2; X is F (1), Br (2) or I (3) and β-diketiminate (NacNac) stabilized In(II) dimer (MesNacNac)2In2Br2 (4) with In–In bond are reported along with the single-crystal X-ray structures of 2–4.