Post-functionalization through covalent modification of organic counter ions: a stepwise and controlled approach for novel hybrid polyoxometalate materials

Abstract

Post-functionalization of Class I type polyoxometalate-organic hybrids through covalent modification of the organic counter ions in a step-wise and controlled manner is reported for the first time. The properties of the post-functionalized hybrids have been studied and compared with those of their parent hybrids revealing marked differences in properties.