Issue 18, 2020

The use of a single ammonium acidic salt towards simple green co-precipitation synthesis for Mn4+-activated fluorides

Abstract

Herein, a simple green co-precipitation route for Mn4+-activated fluorides has been realized via individually using the aqueous acidic salt NH4HF2 as a solvent. The systematic explorations of ionization, erosion, solvent concentration, solvency on reactants, and reaction with an extra weak acid disclosed that the near-saturated aqueous NH4HF2, ionizing into abundant HF2, H+, and F ions, exhibited large dissolving capacity and good stabilization on Mn4+ without obvious toxicity. The green synthesized example of Cs2GeF6:Mn4+ emitted a typical narrow band red light at 633 nm with normal optimal doping at ∼8 at%. Compared with its contrast prepared from the HF system, it experienced only ∼10% reduction in quantum efficiency and slight emission attenuation below 150 °C as the more humidity-sensitive weaker acid surface aroused lattice thermal vibration. The further action as red component fabricated a high-quality warm white light-emitting diode (W-LED) with a high color rendering index (Ra ∼ 91), high luminous efficacy (∼149 lm W−1), low correlated color temperature (∼3211 K), and good color stability against the operating environment. Combined with the universal synthesis of A2XF6:Mn4+ (A = K, Rb, Cs; X = Si, Ge), our findings can probably open up a simple and feasible green synthetic strategy for efficient Mn4+-doped fluorides using acidic salts.

Graphical abstract: The use of a single ammonium acidic salt towards simple green co-precipitation synthesis for Mn4+-activated fluorides

Supplementary files

Article information

Article type
Paper
Submitted
17 Mar 2020
Accepted
31 Mar 2020
First published
31 Mar 2020

Dalton Trans., 2020,49, 5823-5831

The use of a single ammonium acidic salt towards simple green co-precipitation synthesis for Mn4+-activated fluorides

T. T. Deng, E. H. Song, Y. Y. Zhou, J. Y. Chen, Y. F. Cheng, J. Yuan and T. Fan, Dalton Trans., 2020, 49, 5823 DOI: 10.1039/D0DT00986E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements