Issue 26, 2020

Building a robust 3D Ca-MOF by a new square Ca4O SBU for purification of natural gas

Abstract

For the first time, a new square Ca4O SBU is introduced into a 3D Ca-MOF, ([MeNH2]2[Ca4O(MTB)2(EtOH)4])ยท(solvent)n (1), to generate a (4,8)-connected flu-topology structure. Compound 1 exhibits selective adsorption of C3 and C2 hydrocarbons and CO2 over CH4 with especially high IAST selectivities for C3 hydrocarbons over CH4 (at 15/85 and 50/50 ratio) at 298K and 1 bar.

Graphical abstract: Building a robust 3D Ca-MOF by a new square Ca4O SBU for purification of natural gas

Supplementary files

Article information

Article type
Communication
Submitted
13 Mar 2020
Accepted
02 Jun 2020
First published
03 Jun 2020

Dalton Trans., 2020,49, 8836-8840

Building a robust 3D Ca-MOF by a new square Ca4O SBU for purification of natural gas

F. Hu, Z. Di, M. Wu and J. Li, Dalton Trans., 2020, 49, 8836 DOI: 10.1039/D0DT00943A

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