New polymorphism for BaTi(IO3)6 with two polymorphs crystallizing in the same space group

Zhen Qian; Hongping Wu; Hongwei Yu; Zhanggui Hu; Jiyang Wang; Yicheng Wu

doi:10.1039/D0DT00593B

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New polymorphism for BaTi(IO₃)₆ with two polymorphs crystallizing in the same space group†

Zhen Qian,^a Hongping Wu,

^a Hongwei Yu,

*^a Zhanggui Hu,^a Jiyang Wang^a and Yicheng Wu^a

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* Corresponding authors

^a Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystals, Tianjin University of Technology, Tianjin 300384, China
E-mail: hwyu15@gmail.com

Abstract

Polymorphic α- and β-BaTi(IO₃)₆ have been synthesized. They crystallize in the same space group and exhibit highly similar structures. But the different powder X-ray patterns and crystal morphologies indicate that they belong to different phases, which represents the first phase transitions with two polymorphs possessing the same space group and similar cells.

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Article information

DOI: https://doi.org/10.1039/D0DT00593B
Article type: Communication
Submitted: 17 Feb 2020
Accepted: 28 May 2020
First published: 03 Jun 2020

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Dalton Trans., 2020,49, 8443-8447

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New polymorphism for BaTi(IO₃)₆ with two polymorphs crystallizing in the same space group

Z. Qian, H. Wu, H. Yu, Z. Hu, J. Wang and Y. Wu, Dalton Trans., 2020, 49, 8443 DOI: 10.1039/D0DT00593B

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Dalton Transactions