Issue 4, 2020

Switchable on–off spin-crossover properties of iron(ii) compounds by trimming intermolecular hydrogen bonds

Abstract

Reversible single crystal-to-single crystal transformations from [FeL2(NCS)2]·3MeOH (1·3MeOH, L = 2-(anthracen-10-yl)-1H-imidazo[4,5-f][1,10]phenanthroline) to 1 and 1·2H2O were reported, which were accompanied by on–off switching of the spin-crossover properties.

Graphical abstract: Switchable on–off spin-crossover properties of iron(ii) compounds by trimming intermolecular hydrogen bonds

Supplementary files

Article information

Article type
Communication
Submitted
09 Dec 2019
Accepted
28 Dec 2019
First published
30 Dec 2019

Dalton Trans., 2020,49, 998-1001

Switchable on–off spin-crossover properties of iron(II) compounds by trimming intermolecular hydrogen bonds

N. Li, J. Xue, J. Liu, Y. Wang, Z. Yao and J. Tao, Dalton Trans., 2020, 49, 998 DOI: 10.1039/C9DT04685B

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