Ion momentum imaging study of the ion–molecule reaction Ar+ + O2 → Ar + O2+

Abstract

Charge exchange reactions between Ar⁺(²P) and O₂ (X³Σ⁻_g) are investigated in the collision energy range of 3.40–9.24 eV within the center-of-mass coordinate, by using the ion momentum imaging technique. The internal energy of the product O₂⁺ is enhanced gradually with the increase of collision energy, and the forward-scattered O₂⁺ ions are distributed in the broader range of scattering angle at higher collision energies. At the low collision energy of 3.40 eV, the resonant charge transfer, similar to a photon ionization process, leads to the Franck–Condon-like vibrational state population of O₂⁺ at the a⁴Π_u state. At the higher collision energies, besides a⁴Π_u and the high-lying states that are visible in the photoionization process, the O₂⁺ products could be populated at some electronically bound states in the non-Franck–Condon region. The present observations indicate again the strong collision-energy dependences of the charge exchange reactions, but distinctly different from our previous findings for Ar⁺ + NO → Ar + NO⁺.