Issue 47, 2020

Polyoxometalate-based hydrogen-bonded organic frameworks as a new class of proton conducting materials

Abstract

To develop new types of crystalline proton conducting materials for fuel cells, a polyoxometalate-based hydrogen-bonded organic framework (PHOF) based on Keggin-type [PMo12O40]3− and phenylimidazole (PHOF 1) has been prepared. AC impedance analysis shows that the highest proton conductivity of PHOF 1 reaches up to 2.02 × 10−4 S cm−1 (100 °C, 98% RH).

Graphical abstract: Polyoxometalate-based hydrogen-bonded organic frameworks as a new class of proton conducting materials

Supplementary files

Article information

Article type
Communication
Submitted
29 Oct 2020
Accepted
10 Nov 2020
First published
10 Nov 2020

CrystEngComm, 2020,22, 8161-8165

Polyoxometalate-based hydrogen-bonded organic frameworks as a new class of proton conducting materials

N. Ji, Z. Shi, X. Xie and G. Li, CrystEngComm, 2020, 22, 8161 DOI: 10.1039/D0CE01578D

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