Issue 34, 2020
From the journal:

CrystEngComm

Observation of three different linker conformers in a scandium ferrocenedicarboxylate coordination polymer†

Jannik Benecke,a   Erik Svensson Grape, ORCID logo b   Tobias A. Engesser,a   A. Ken Inge ORCID logo b  and  Helge Reinsch ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry, Christian-Albrechts-Universität, Max-Eyth Straße 2, D-24118 Kiel, Germany
E-mail: hreinsch@ac.uni-kiel.de

b Department of Materials and Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden

Abstract

Electron and powder diffraction were combined to elucidate the structure of the new coordination polymer [Sc2(FcDC)3] based on 1,1′-ferrocenedicarboxylate (FcDC2−), denoted as CAU-50. Remarkably, three different conformers of the very same linker molecule are observed, two of which serve as connectors for the scandium cations while one conformer acts as capping agent.

Graphical abstract: Observation of three different linker conformers in a scandium ferrocenedicarboxylate coordination polymer

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Article information

DOI
https://doi.org/10.1039/D0CE00986E
Article type
Communication
Submitted
08 Jul 2020
Accepted
12 Aug 2020
First published
12 Aug 2020

CrystEngComm, 2020,22, 5569-5572

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Observation of three different linker conformers in a scandium ferrocenedicarboxylate coordination polymer

J. Benecke, E. Svensson Grape, T. A. Engesser, A. K. Inge and H. Reinsch, CrystEngComm, 2020, 22, 5569 DOI: 10.1039/D0CE00986E

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