We herein present two polymeric solid state structures of pmdta-stabilized methyllithium with co-existing dimeric and tetrameric units, exhibiting partial incorporation of nearly omnipresent LiCl selectively in the dimeric entities. An unexpected interconnecting contact from these positions to a neighboring tetrameric unit is observed.
L. Knauer and C. Strohmann, Chem. Commun., 2020, 56, 13543 DOI: 10.1039/D0CC05547F
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