Issue 85, 2020

8-Aminoquinoline as a bidentate traceless directing group for Cu-catalyzed selective B(4,5)–H disulfenylation of o-carboranes

Abstract

A traceless bidentate directing group guided copper catalyzed direct cage B(4,5)–H disulfenylation of o-carboranes has been achieved, leading to a series of B(4,5)–disulfenylated o-carborane derivatives in high yields with excellent regioselectivity. The in situ departure of the 8-aminoquinoline bidentate auxiliary circumvents additional processes for directing group removal, thus enhancing the atom-/step-economy.

Graphical abstract: 8-Aminoquinoline as a bidentate traceless directing group for Cu-catalyzed selective B(4,5)–H disulfenylation of o-carboranes

Supplementary files

Article information

Article type
Communication
Submitted
31 Jul 2020
Accepted
18 Sep 2020
First published
18 Sep 2020

Chem. Commun., 2020,56, 12997-13000

8-Aminoquinoline as a bidentate traceless directing group for Cu-catalyzed selective B(4,5)–H disulfenylation of o-carboranes

Y. Chen, Y. Quan and Z. Xie, Chem. Commun., 2020, 56, 12997 DOI: 10.1039/D0CC05207H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements