Ganorbifate A featuring an unprecedented 6/6/6/5/5 pentacyclic system, and ganorbifate B with an unusual 6/4/6/5/8/5 ring system were isolated from the fruiting body of Ganoderma orbiforme. Their structures were established using extensive spectroscopic analysis, including DFT calculations of NMR data and ECD spectra.
X. Yin, T. M. L. Tuong, J. Tian, G. Pescitelli and J. Gao, Chem. Commun., 2020, 56, 10195 DOI: 10.1039/D0CC04679E
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