Stabilizing black phosphorus via inorganic small-molecular H3BO3

Fangbing Shi; Xuanchen Dong; Keke Huang; Zhibin Geng; Xiyang Wang; Xiaotian Yang; Chao Wang; Wei Zhang; Shouhua Feng

doi:10.1039/D0CC04618C

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Stabilizing black phosphorus via inorganic small-molecular H₃BO₃†

Fangbing Shi,^a Xuanchen Dong,^a Keke Huang,

^a Zhibin Geng,^a Xiyang Wang,^a Xiaotian Yang,

^b Chao Wang,^b Wei Zhang

^c and Shouhua Feng

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
E-mail: shfeng@jlu.edu.cn

^b Key Laboratory of Architectural Cold Climate Energy Management, Ministry of Education, Jilin Jianzhu University, Changchun 130118, China

^c Electron Microscopy Center, School of Materials Science & Engineering, Jilin University, Changchun 130012, China

Abstract

Taking the degradation mechanism into consideration, inorganic small-molecular H₃BO₃ was selected for surface coordination of black phosphorus (BP). The successful coordination between BP and H₃BO₃ not only improves the ambient stability of BP, but also preserves the intrinsic properties of BP without distorting its structure.

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Article information

DOI: https://doi.org/10.1039/D0CC04618C
Article type: Communication
Submitted: 03 Jul 2020
Accepted: 10 Aug 2020
First published: 14 Aug 2020

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Chem. Commun., 2020,56, 11418-11421

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Stabilizing black phosphorus via inorganic small-molecular H₃BO₃

F. Shi, X. Dong, K. Huang, Z. Geng, X. Wang, X. Yang, C. Wang, W. Zhang and S. Feng, Chem. Commun., 2020, 56, 11418 DOI: 10.1039/D0CC04618C

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Chemical Communications