Issue 78, 2020
From the journal:

Chemical Communications

Iron-catalysed 1,2-aryl migration of tertiary azides†

Kaijie Wei, ORCID logo a   Tonghao Yang,‡a   Qing Chen,a   Siyu Lianga  and  Wei Yu ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Abstract

1,2-Aryl migration of α,α-diaryl tertiary azides was achieved by using the catalytic system of FeCl2/N-heterocyclic carbene (NHC) SIPr·HCl. The reaction generated aniline products in good yields after one-pot reduction of the migration-resultant imines.

Graphical abstract: Iron-catalysed 1,2-aryl migration of tertiary azides

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Article information

DOI
https://doi.org/10.1039/D0CC04579A
Article type
Communication
Submitted
02 Jul 2020
Accepted
22 Aug 2020
First published
24 Aug 2020

Chem. Commun., 2020,56, 11685-11688

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Iron-catalysed 1,2-aryl migration of tertiary azides

K. Wei, T. Yang, Q. Chen, S. Liang and W. Yu, Chem. Commun., 2020, 56, 11685 DOI: 10.1039/D0CC04579A

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