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Issue 73, 2020
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Poly(hydroxyurethane): catalytic applicability for the cyclic carbonate synthesis from epoxides and CO2

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Abstract

We have developed a synthetic methodology using poly(hydroxyurethane) as an organocatalyst for the chemical fixation of CO2 into epoxides, leading to the formation of five-membered cyclic carbonates with remarkably high selectivity and yields. The catalyzed reaction was applicable to various epoxides.

Graphical abstract: Poly(hydroxyurethane): catalytic applicability for the cyclic carbonate synthesis from epoxides and CO2

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Article information


Submitted
28 Jun 2020
Accepted
04 Aug 2020
First published
05 Aug 2020

Chem. Commun., 2020,56, 10678-10681
Article type
Communication

Poly(hydroxyurethane): catalytic applicability for the cyclic carbonate synthesis from epoxides and CO2

S. Motokucho and H. Morikawa, Chem. Commun., 2020, 56, 10678
DOI: 10.1039/D0CC04463F

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