Regulating surface sulfonation on cellulose nanocrystals and self-assembly behaviors†
Abstract
Gradiented sulfonation was performed for the surface modification of cellulose nanocrystals by conjugate addition with sodium vinyl sulfonate moieties. The self-assembly behaviors of the modified nanocrystals in the liquid state as suspensions and in the solid state as films were regulated by their surface chemistry and crystalline properties.

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