Cation- and anion-ordered rutile-type derivative LiTeO3(OH)

Kotaro Fujii; Yume Yoshida; Yue Jin Shan; Keitaro Tezuka; Yoshiyuki Inaguma; Masatomo Yashima

doi:10.1039/D0CC04074F

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Cation- and anion-ordered rutile-type derivative LiTeO₃(OH)†

Kotaro Fujii,

^a Yume Yoshida,^b Yue Jin Shan,^b Keitaro Tezuka,^b Yoshiyuki Inaguma

^c and Masatomo Yashima

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1-W4-17, O-okayama, Meguro-ku, Tokyo, Japan
E-mail: yashima@cms.titech.ac.jp

^b Department of Fundamental Engineering, School of Engineering, Utsunomiya University, 7-1-2 Yoto, Utsunomiya, Tochigi 321-8585, Japan

^c Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan

Abstract

The first example of both cation- and anion-ordered rutile-type derivative LiTeO₃(OH) (= HLiTeO₄) has been discovered. LiTeO₃(OH) belongs to a non-centrosymmetric space group P2₁. Both cations (Li⁺/Te⁶⁺) and anions (O²⁻/OH⁻) exhibit occupational ordering in LiTeO₃(OH).

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Article information

DOI: https://doi.org/10.1039/D0CC04074F
Article type: Communication
Submitted: 11 Jun 2020
Accepted: 22 Jul 2020
First published: 23 Jul 2020

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Chem. Commun., 2020,56, 10042-10045

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Cation- and anion-ordered rutile-type derivative LiTeO₃(OH)

K. Fujii, Y. Yoshida, Y. J. Shan, K. Tezuka, Y. Inaguma and M. Yashima, Chem. Commun., 2020, 56, 10042 DOI: 10.1039/D0CC04074F

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