Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(II) iodide ion-triplet complex

Mingyeong Shin; Sujin Seo; In-Hyeok Park; Eunji Lee; Yoichi Habata; Shim Sung Lee

doi:10.1039/D0CC03902K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(ii) iodide ion-triplet complex†

Mingyeong Shin,

^a Sujin Seo,

^a In-Hyeok Park,

^ab Eunji Lee,

^ac Yoichi Habata

^c and Shim Sung Lee

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 52828, South Korea
E-mail: sslee@gnu.ac.kr

^b Graduate School of Analytical Science and Technology (GRAST), Chungnam National University, Daejeon 34134, South Korea

^c Department of Chemistry, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan

Abstract

A combination of pillar[5]-bis-trithiacrown (L) and mercury(II) halides afforded a monomer complex (Cl⁻-form), a 1-D coordination polymer (Br⁻-form) and a supramolecular ion-triplet complex [(I·Hg·I)@L] (I⁻-form). In the ion-triplet complex, the host encapsulates the (I⁻–Hg²⁺–I⁻) entity via Hg²⁺⋯π and C–H⋯I⁻ interactions, reflecting geometrical complementarity.

This article is part of the themed collection: Celebrating the 75th Anniversary of the Korean Chemical Society (KCS)

Download options Please wait...

Associated articles

Correction: Metallosupramolecules of pillar[5]-bis-trithiacrown including a merc…

Supplementary files

Article information

DOI: https://doi.org/10.1039/D0CC03902K
Article type: Communication
Submitted: 03 Jun 2020
Accepted: 24 Jul 2020
First published: 24 Jul 2020

Download Citation

Chem. Commun., 2020,56, 10135-10138

Permissions

Request permissions

Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(II) iodide ion-triplet complex

M. Shin, S. Seo, I. Park, E. Lee, Y. Habata and S. S. Lee, Chem. Commun., 2020, 56, 10135 DOI: 10.1039/D0CC03902K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(ii) iodide ion-triplet complex†

Abstract

Associated articles

Supplementary files

Article information

Download Citation

Permissions

Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(II) iodide ion-triplet complex

Social activity

Search articles by author

Spotlight

Advertisements